When I first started working with peregrines, all the information pointed at mortality among juvenile peregrines being close to 70% (7 out of 10 died) in the first year - that's for wild peregrines regardless of where they nest, buildings or cliff-faces. Now the numbers are down to about 50% on average. Now whether that number is because of projects like ours, or more data so more accurate statistics or a combination of both, the point is that even in the wild away from glass buildings, mortality among peregrines is at its greatest among juveniles in the first few months of life. So yes, it would be wonderful if they didn't fly into buildings, however, we have veterinary and rehabilitation assistance for "our" birds which the cliff peregrines do not have. Are there more hazards in an urban environment, I think it is probably pretty a 50:50 split, different hazards and benefits.
So yes, the loss of a chick, particularly as a result of a collision with a building/window/whatever, is disheartening and unfair, mortality among young chicks is high everywhere. Here at least we have the people and services that if there is a problem we have a chance to help them. Cliff-nesting peregrines rarely get that kind of a second-chance.